^
And turn on the bathroom fans.
TSP, the former "King":
https://homeguides.sfgate.com/why-are-phosphates-in-detergent-so-dangerous-12268795.htmlquoting the link:
History
Phosphates began to replace soap for household purposes after World Way II, due to availability of resources
and a growing problem of poor cleaning performance due to hard water.
Negative Impact
Phosphates carry into waste systems and are hard to break down by ordinary wastewater processing systems. As they carry into streams, lakes and rivers, they increase algae growth and subsequently decrease the oxygen that is needed for healthy aquatic life, and contribute to the pollution of water bodies.
end quote
I believe some cleaners like dishwasher detergents still contain trisodium phophate (TSP), the effective evil ingredient, You might try a solution of Calgon. I also seem to recall that some farm stores sold TSP-based cleaners, but that might be obsolete information.
I never tried this, but I suspect that a generous sprinkling of table salt sprayed lightly with water would loosen things up. Seems the sodium would replace the calcium "soapate" in enough of the scum molecules of calcium "soapate" to loosen things up.
NaCl + Calcium "soapate" ->(partial reaction) Na "soapate" (soluble) and calcium chloride (also soluble.)
Just looks that way to me.
Caution: After you clean the tub it will be very slippery.
I used to think that environmental concerns were all "good," and made the world a better place to live in, but as regulations get more and more onerous, I'm starting to wonder about that. I was thinking the other day that EPA should stand for Excessive Prohibitions Agency. I'm sure I'm not the first to think that.
Terry, 230RN