Mead-maker here.
Crown caps do not retain pressure well. They'll hold in-bottle carbonation for beer most of the time, but they cannot handle the pressure generated by an in-bottle carbonated champagne, sparkling wine, or mead. Either wine corks or champagne/mushroom corks with wire retainers are needed for that threshold of pressure. With an appropriately stout glass vessel.
I think the worst that would happen is your crown caps would burst and fly off. They shouldn't hold to the threshold that the bottle bursts rather than the cap, but I have heard of people's 12oz beer bottles bursting from the process sometimes.
As for autoclaving or pressure cooking a filled bottle with yeast/wort? I think you'd kill the starter culture along with any undesired elements. Raising any wort or starter above 80 degrees or so is generally bad for the yeast you want to ferment. Hitting pasteurization or higher will kill it just like any other unwanted contaminant. When I get a mash going from grain, I let it steep in the laudening tun for a good hour or so starting at about 150* and it typically comes back out around 125*. My tun is a 5 gallon Home Depot water jug that I've put a better spout on that I can throttle nice and low for a slow drain, and a wire mesh hose on that spout's inside connection to filter the grains.
After I go through grain extraction, I boil my hops for the appropriate time and then I have to rapidly cool my mash in order for it to be safe to add my yeast, otherwise it will die just about instantly. In a target 5 gallon batch, my hopped mash will usually be about 2-3 gallons of very high gravity liquid. I'll do some calculations for a desired fermentation starting gravity and add 1.5 to 2.5 gallons of either cubed ice or refrigerated water and stir vigorously until the mash temperature hits 80 degrees. Often times I'll have to give the mash an ice bath in the sink since adding the right amount of water or ice will only bring it to 120* or so, and that's still way too high.
I don't do starters, I just pop a yeast packet into whatever I'm making, so I can't help you with this one other than to say just sanitize your 12oz bottles and caps in sani-clean or similar sanitizer, fill them with your starter, and cap 'em. Pretty sure they'd be fine. A jug of sani-clean lasts me 15-20 brews, comes out to less than a buck per batch.