Copper is essentially maintenance free.
The green layer that forms over the face of the copper is amazingly good at protecting the roof long-term. No painting necessary for copper, but the initial cost, especially today, is just insane.
And, until you get that beautiful patina built up, anywhere from 3 to 10 years, it looks like hell. Some companies offer chemical treatments that give the patina a kick start. How effective they are I don't know.
Of course, you still need to attend to the flashing, any fasteners there might be, and valleys.
That's no different than a shingle roof, actually. If you neglect the valleys on a shingle roof, you will eventually have leaks.