I'm assuming it's an ATX supply since AT supplies have separate lines for power on/off.
If 20 pin, short pin 14 to any black wire pin.
If 24 pin, short pin 16 to any black wire pin.
Whatever pin it is, the wire to it should be green or gray. To verify that it's the right pin, plug the supply in and probe that pin. It should read 5VDC referenced to a black wire pin. All other pins should read 0VDC.
Oh yeah, it may be a Dell specific unit and have a Dell specific connector arrangement. The physical connector will still look the same and plug in normally though. You should be able to differentiate it by checking pin 11. On a standard ATX supply, pin 11 will be a yellow +12VDC line. On a Dell specific supply, it's a gray Power On line and will read +5VDC if the supply is plugged in. If that's the case, it's probably better to not use it for this application.