Clean away the rust. Fit a 6 sided socket to the nut. Do not use a 12 pt, as they will slip and spin.
The six pt. offers a better application of force to the fastener (Physicists, have your say).
If corrosion has eaten away the metal to the point that the proper size wrench no longer fits, modify the fastener with grinder/file/etc to fit the next smallest wrench.
You want a tight fit.
Special Tools
tm are also available to grip these corroded fasteners.
http://www.lislecorp.com/divisions/products/?product=67&division=1&category=11Attach a long
1/4" extension (up to 8 or 12" if you have room) and use a 3/8"-1/4" adapter as needed.
Step up to a 3/8" ratchet.
Utilize it like a hand operated impact wrench, bouncing torque with your wrist into the stuck fastener.
ALSO if you've got room, like when accessing manifold bolts through a wheel well or downpipe bolts with the car on a hoist, you can use the aforementioned 8"x 1/4" extension on an impact wrench AND GO SLOW.
The 1/4" extension introduces flex into the system, softening the blow. The stuck fastener will be "pushed" rather than "smacked" reducing the opportunity for snapped studs.
Like French, I do a couple of rounds of pb blaster or Kroil (preferred) for a few days and heat/cool cycles.
Or just use a nut splitter.
After laying on your back in the snow for two hours spinning rounded nuts with a hammer and punch you'll agree that this model
http://buy1.snapon.com/catalog/item.asp?P65=&tool=all&item_ID=8967&group_ID=1019&store=snapon-store&dir=catalogis worth every penny.
Reassemble using new nuts and spray-on copper anti-seize.