I often wondered, if you had a large bubble underwater, with some way to prevent it from floating upward due to buoyancy, what would be the steady-state composition of the atmosphere in that bubble?
Obviously humidity would be 100%. There is some dissolved oxygen in water--that's how fish live. Eventually, the vapor pressure of oxygen and CO2 in the bubble would come to equilibrium with the dissolved oxygen and CO2 in the water. For a large enough bubble, the presence of a human in the bubble wouldn't perturb the atmosphere as the whole water/air surface is exchange surface. Under what depth/temperature conditions could a human live in a "large" bubble? Are there any?