They make them in blue for diesel, yes.
Diesel cans should be yellow. Blue is for kerosene. Potable water jugs also tend to be blue. One would hope that the user can tell the difference between water and kerosene.
I kept one of the WalMart 5gal plastic jerrycan type containers on the porch at the old house for a long time, and it never cracked from freezing. The shape has a definite advantage when you're storing it, though the 7.5 gallon water cube they carry is also pretty good, and has a spout so you can refill smaller containers without having to lift it.
Generally for the Blazer, I just carry a case or two of the cheapest 1L or similar size bottled water in the rear floorboard. It would take a while to fill the radiator, but it's a lot more practical if I just want a drink or end up on foot and want to carry a couple bottles rather than a gallon jug. In my wife's car, I keep three full military canteens, a carrier, enough Chlor-Floc tablets to refill the canteens twice, and an empty collapsible 2gal jug.