i can't imagine swimming 101 meters on the surface with one breath, much less a 202 meter round trip. that's over 1/10th of a mile!
I've done 100 yards, in a 25-yard pool so 4 wall push-offs. It was not easy and that's on the surface. Completely underwater I've done 50 meters. Sinking down is obviously less effort than swimming laterally, but that is not the amazing part of all this.
The most amazing part is the pressure! 101 meters is approx 333 feet, which is really close to 10 atmospheres of pressure. This means that his lungs will be compressed to 1/11 their inflated size. It's hard to tell in the dim light but at the bottom of his descent, he looks like he lost about 20 lbs on the way down. That's due to his rib cage being crushed to its minimum size, and all his internal organs being pulled up out of his gut into his rib cage.
Forget the hypoxia for a second and just think of the amount of training and conditioning it takes to mechanically survive that. How many dives does he have to do, working up to that depth slowly over years, to be able to stretch his body in that way.