Avast, Lookout is also good.
Amazon (several different ones actually...) if you are into Amazon they have apps for different functions.
Android Assistant, help to manage the thing. App monster as well.
Congress, gives info on congress and upcoming festivities.
Angry Birds of course.
Dolphin Browser HD, much better than the stock internet browsers
If you facebook, the facebook app is handy.
Flashlight app is nifty/useful especially if your phone has a flash camera.
Juice Defender, helps keep your battery longer by helping to manage power usage.
LOL Droid. If you like LOL Cats, Very Demotivational, etc. this app is great
If you will use it as an MP3 player, I like MixZing
Netflix if you have an account and want to stream movies.
Shazam, hear a song and like it? Shazam will tell you the title, artist, etc.
Tapatalk, useful for forums. APS is on tapatalk
The Federalist Papers
US Constitution
The Weather Channel
KnotsGuide
Army Survival Manual
Also check out for your bank or credit cards if you feel so inclined. Many have apps. Also if you can find an app to do something through it rather than the browser, like tapatalk for forums, I find it much better.
Basically play around with it if anything else comes to mind you would like. Odds are there is an app for it, and on a lot of things there are several so you can play with them and go with what you like best. Also most anything that comes in an app will be better than what probably is on the phone (like the browser)