See, now that is very interesting because the definition of an "amp" is one coulomb of electrons passing any given point (IIRC) (Apparently I do) : http://www.britannica.com/science/coulomb
But that may not necessarily be true?
It's absolutely true..,there are just an assload of electrons in play.
Copper has about 8x10^23 electrons per cubic cm.
One coulomb is ~6x10^18 electrons
So if you have current density in amps/cm
1 A/cm2 = 1 coulomb/s moving through that square cm
So let's say the "wire" is 1cm long
1 amp through this stubby wire means ~6x10^18 electrons moved into one face, and the same moved out the other side, and all the ones in the middle just moved a little bit
(And they all rolled over and one fell out...)
So the speed is 6x10^18 / 8x10^23 cm/s per amp/cm2
Or ~7.5x10^-6 cm/s
Now, most wires typically carry several amps per square mm, so the velocity in those is 2-300x as high
Which means ~1.5x10^-3 cm/s
So after an hour...the electrons only move about 2 inches. And that is at a few amps/mm2 (a bunch)
^ That what I was thinking, especially in terms of things like electroplating and current through a vacuum tube (valve) or cathode-ray tube (CRT).
<Section on points of confusion deleted.>
Noting birdman's qualification of "in a wire," I reckon I'd better read up on his suggestion to do some googling.
Terry, 230RN
Math works here too.
This is why electroplating takes so much current...effectively, 1 amp for 1 second is 1/100,000 of a mole of electrons...and most electroplating processes are 1 electron = 1 atom deposited.
So for copper that means 1 amp for 1 second = 1/100,000 of a mole = ~640 -micrograms- of copper
(For 1 mil thick copper that's ~3 square mm)
So think about the last time you electroplated copper...a board 10cm square on both sides with 1 mil (25um) copper takes about 6700 amp-seconds, or ~2A for an hour...seems about right, right?
But the speed of the electrons is still pretty slow...a 1 molar electrolyte solution has ~6x10^20 electrons per cm3, so in the above circuit board example, the current per unit area is 0.01A/cm2, or 6x10^16 electrons/cm2/s...so the electrons are moving in the so,union at ~1/10,000 cm/s
For CRTs, again, let's do the math.
The beam current is <100 micro amps, or about 10^15 electrons per second.
Now, the fun part. Let's assume a 1.5 megapixel display at 60hz refresh, with a 0.3mm dot pitch
That's 10^8 pixels/s, each of which gets ~10^7 electrons
slight digression:
The raster dot has to move about (10^8 * 0.3mm) 30 million mm/s (neato, the dot moves laterally at 30,000m/s, or 0.01% the speed of light).
Ok, back
Since the electron velocity has to be sufficient to put 10^7 electrons into the 0.3mm wide pixel in 10^-8 seconds, we can assume the electron ps have to move faster than 0.3mm in 10^-8 seconds (for a 45deg beam angle...most are less than this, meaning slightly slower electrons, but for this calc, that's fine)
So here the electrons are moving at 0.3*10^8 mm/s, or 30,000m/s!!
so here the electrons are moving 10 billion times faster than in the electrolyte (even though the current per unit area is 100uA/0.3mm Diameter, 0.14 A/cm2 is 10x as high as the electrolyte, and 10x smaller than the wire).
BUT the electron density is ~10^7 electrons in this 0.3mm diameter, 0.3mm long packet, or an electron density of 10^7 electrons in 1/50,000 of a cm3, or 5x10^11 electrons per cubic cm...which is a -billion- times smaller than in the electrolyte solution!
So now, the 10 billion times faster makes sense...the average electron speed goes up with current density, and down with electron density--so one billionth the electron density = one billion times faster, and 10x the current per unit area = 10x faster than that = 10 billion.
Basically...what we just discovered is the origin of resistance in a way--in the CRT, thousands of volts are needed to move that current density across a few 10's of cm...in the electrolyte, a few volts, and in the copper, a few millivolts (note, its kinda apples and oranges here, but the general trend is what I'm talking about).
For metals, the more free mobile electrons Ina given volume, the slower the electrons need to move for a given current = the less energy of each lost when the collide with an atom = the less electromotive force (voltage) needed to get them moving again = the lower the resistance.
(There are many other effects...like it's actually atom dependent on how much the electron is attracted to the atom and how much EMF it takes to make it mobile again...which is why silver is more conductive than gold, but again, I digress)
One easy way to examine this:
Measure the resistance of a glass of water...
Add a little salt and dissolve...
Measure again...
Keep adding salt (waiting for it to dissolve) and measuring
Th resistance will keep decreasing because you are adding more and more mobile charge carriers = slower movement = less voltage required to keep them moving = lower resistance (voltage required to move a given charge at a given velocity :) )