Dexcool uses organophosphates and silicates that were, at one time, better at holding back the corrosion and electrolysis inherent in mixed-metal engine configurations (aluminum heads, iron block). Now, all coolants have taken that into account. The only real issue now is mixing PG coolants with Dexcool. Instant sludge. The only way to use PG based coolant in a Dex-filled engine is a complete flush, and a damned thorough one at that. Any little bit of Dex left will bring on Very Bad Things.
Brad